Connect to your vcenter server and click on the Warning message to display certificate \\
Select Export and export the certificate as PKCS#7 certificate chaine  \\
Open then URL: https://vcenterurl/certs/download.zip \\
Save the file and extract the win folder \\
Import all certs that are found in that folder in the Trusted Root Certification Authorities folder\\

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The Vcenter self signed certificate will now be trusted in Chrome as all Trusted authorities are now know